Stain removal is all about speed and technique. Here's the proven method for tackling rust stains effectively.
Squeeze lemon juice onto the rust stain and cover with salt. Let it sit in the sun for 2-3 hours. The citric acid dissolves rust while salt absorbs it.
Scrub the stain with a soft brush. Rinse with cold water. Repeat if the stain remains.
Spray undiluted white vinegar on rust stains on tile, porcelain, or concrete. Let it sit 30 minutes, then scrub.
For clothing, wash normally after lemon treatment. Don't use bleach -- it sets rust stains permanently.